A Ni(i)Fe(ii) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases.

نویسندگان

  • Carlo U Perotto
  • George Marshall
  • Graham J Jones
  • E Stephen Davies
  • William Lewis
  • Jonathan McMaster
  • Martin Schröder
چکیده

[Ni(L(1))Fe((t)BuNC)4](PF6)2 is a robust Ni(II)Fe(II) complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L(1))Fe((t)BuNC)4](+) is an unprecedented Ni(I)Fe(II) species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.

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عنوان ژورنال:
  • Chemical communications

دوره 51 95  شماره 

صفحات  -

تاریخ انتشار 2015